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XIANG Xinyue，YE Guohua，ZHU Siqin，RONG Yiyang，ZHANG Yun，SONG Changxu．Solvent extraction of vanadium from vanadium−bearing acid leaching solution[J]. Conservation and Utilization of Mineral Resources，2023，43（5）：170−178. DOI: 10.13779/j.cnki.issn1001-0076.2023.07.008
Citation: XIANG Xinyue，YE Guohua，ZHU Siqin，RONG Yiyang，ZHANG Yun，SONG Changxu．Solvent extraction of vanadium from vanadium−bearing acid leaching solution[J]. Conservation and Utilization of Mineral Resources，2023，43（5）：170−178. DOI: 10.13779/j.cnki.issn1001-0076.2023.07.008
shu

Solvent Extraction of Vanadium from Vanadium−bearing Acid Leaching Solution

  • Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China

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  • Received Date: December 28, 2022
  • Issue Publish Date: October 30, 2023
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    • Abstract

  • Aiming at the problem of vanadium purification and enrichment for vanadium-containing acid leaching solution, the research progress of vanadium extraction is reviewed. In conventional extraction, acidic phosphorus extractant has the advantages of high efficiency of vanadium extraction and fast phase separation, but its impurity removal is not complete and requires a large amount of acid. The alkaline amine extractant has good selectivity and thorough impurity removal, but it is easy to produce the third phase. Chelating extractant can shorten the extraction process, and the free acid in the raffinate can also be recycled, which has good economic benefits, but its degradation problem has not been solved. Among the new extraction methods, the liquid membrane extraction process is simple, the mass transfer efficiency is high, and the metal ion enrichment ratio is high. However, it has the disadvantages of long extraction process, large dosage of reagents, and high organic phase loss. Ionic liquids have many advantages, but they cannot be put into large−scale production and application due to their high preparation cost. Microemulsion extraction has the advantages of fast separation speed, high separation efficiency, and good selectivity, but it will produce ammonia nitrogen wastewater. In recent years, synergistic extraction has been widely studied, but how to effectively inhibit its antagonistic effect and make it fully play its role needs further study.

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