Citation: | CHEN Hao, REN Zijie, GAO Huimin, XIE Yahong, XING Baobao, WANG Zengzi. Experimental Study on Low-temperature Flotation of Quartz-type Fluorite with Petroleum Sodium Sulfonate[J]. Conservation and Utilization of Mineral Resources, 2020, 40(3): 135-139. DOI: 10.13779/j.cnki.issn1001-0076.2020.07.006 |
For quartz-type fluorite ore with CaF2 content of 47.48% and SiO2 content of 39.70%, it is difficult to obtain a good selection index using a conventional fluorite flotation collector of sodium oleate in a low-temperature pulp environment. In order to improve the flotation effect of the fluorite ore at low temperature, flotation experiments were conducted using sodium petroleum sulfonate collector (PSK-13) with good low-temperature resistance. The results showed that the CaF2 grade of 98.57% and the FC-98 fluorite concentrate recovery of 75.02% could be obtained by the process of "closed flotation circuit of one roughing, six cleaning and middling returned cyclically" with the regulator of sodium carbonate, the depressant of water glass and the collector of PSK-13 when the pulp temperature is 5 ℃, which provided a technical reference for the low-temperature flotation. The results of the adsorption amount experiment showed that the adsorption amount of PSK-13 fluorite on the surface changed little and is greater than the adsorption amount of sodium oleate from 5 ℃ to 30 ℃, showing the good performance of low-temperature collection.
[1] |
方遒.安徽某难选萤石选矿试验研究[J].湖南有色金属, 2017, 33(3):16-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hnysjs201703005
|
[2] |
GAO Z, FAN R, RALSTON J, et al. Surface broken bonds:An efficient way to assess the surface behaviour of fluorite[J]. Minerals Engineering, 2019, 130:15-23. http://cn.bing.com/academic/profile?id=ef92468619264caee148297fc08b3dff&encoded=0&v=paper_preview&mkt=zh-cn
|
[3] |
ZHU H, QIN W, CHEN C, et al. Interactions Between Sodium Oleate and Polyoxyethylene Ether and the Application in the Low-Temperature Flotation of Scheelite at 283K[J]. Journal of Surfactants and Detergents, 2016, (6):1289-1295. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=831bee76ef8839f6731636cc8ff25613
|
[4] |
吕子虎, 卫敏, 吴东印, 等.新型捕收剂在萤石浮选中的应用研究[J].矿冶工程, 2013, 33(5):56-58. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kygc201305014
|
[5] |
周玉才, 朱一民, 周菁.某萤石矿低温浮选试验研究及工业实践[J].湖南有色金属, 2014, 30(2):15-19. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hnysjs201402005
|
[6] |
张晓峰, 朱一民, 周菁, 等.细粒难选石英型萤石矿低温浮选试验研究[J].有色金属(选矿部分), 2015(2):39-43. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjs-xk201502009
|
[7] |
朱一民, 陈文胜, 张晓峰, 等.白钨浮选尾矿回收萤石低温浮选试验研究[J].矿产综合利用, 2014(1):25-27. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kczhly201401006
|
[8] |
许霞.DW-1捕收剂低温浮选某石英型萤石矿的试验研究[D].长沙: 中南大学, 2014. http://cdmd.cnki.com.cn/Article/CDMD-10533-1014406856.htm
|
[9] |
许海峰, 钟宏, 王帅, 等.一种新型环己烯羧酸的合成及其对萤石的浮选性能[J].中国有色金属学报, 2014(11):2935-2942. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgysjsxb201411033
|
[10] |
ZHANG Y, SONG S. Beneficiation of fluorite by flotation in a new chemical scheme[J]. Minerals Engineering, 2003, 16(7):597-600. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=60ce0f4b431ad702823df0ec5a5dabf3
|
[11] |
黄俊玮, 张成强, 王守敬, 等.新型药剂体系在某石英脉型萤石矿浮选中的应用[J].矿产保护与利用, 2018(3):130-134. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=6f1ca271-0472-4536-901e-2fdd105e6e95
|
[12] |
DENG L, ZHAO G, ZHONG H, et al. Investigation on the selectivity of N-((hydroxyamino)-alkyl) alkylamide surfactants for scheelite/calcite flotation separation[J]. Journal of Industrial and Engineering Chemistry, 2016, (33):131-141. https://www.researchgate.net/publication/282582505_Investigation_on_the_selectivity_of_N-hydroxyamino-alkyl_alkylamide_surfactants_for_scheelitecalcite_flotation_separation
|
[13] |
KIENKO L A, SAMATOVA L A, VORONOVA O V, et al. Lower temperature flotation of carbonate fluorite ores[J]. Journal of Mining Science, 2010, 46(3):317-323. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=e1d24fef0503859a437d63324e6a0dbe
|
[14] |
张行荣, 朴永超, 尚衍波, 等.一种耐低温型捕收剂在萤石浮选中的应用[J].矿产综合利用, 2015(3):28-31. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kczhly201503007
|
[15] |
岳岩.新型低温萤石捕收剂DL-06对内蒙古某萤石矿选矿试验研究[J].内蒙古科技与经济, 2013(4):44-45. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=nmgkjyjj201304023
|
[16] |
王志安.石油磺酸盐的合成及性能研究[D].青岛: 中国石油大学, 2008. http://cdmd.cnki.com.cn/Article/CDMD-10425-2008199807.htm
|
[17] |
聂光华, 孙体昌, 李帅, 等.黔西南某碳酸盐型萤石矿浮选试验研究[J].矿业研究与开发, 2014(4):82-84. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kyyjykf201404022
|
[18] |
岳涛.微细粒级黑钨矿浮选动力学研究[D].赣州: 江西理工大学, 2013. http://cdmd.cnki.com.cn/Article/CDMD-10407-1014101795.htm
|
[19] |
李明阳, 高惠民, 任子杰, 等.含水铝氟石萤石矿的提纯试验研究[J].非金属矿, 2019, 42(6):68-71. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fjsk201906018
|
[20] |
姚建云, 高惠民, 张孝平, 刘思, 喻福涛, 任子杰.低品位萤石尾矿回收萤石试验研究[J].化工矿物与加工, 2016(1):15-18. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgkwyjg201601005
|
[21] |
艾光华, 梁焘茂, 袁勤智, 等.某低品位方解石-石英型萤石浮选试验研究[J].非金属矿, 2018, 41(1):70-72. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fjsk201801021
|
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刘斌. 某低品位石英型萤石矿选矿试验研究. 现代矿业. 2022(08): 178-180+184 .
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李育彪,杨旭. 萤石浮选药剂及浮选机理研究进展. 金属矿山. 2022(10): 122-129 .
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唐远,朱奥妮,陈琲琲,程晨,李智力,张翼,何东升. 我国战略性非金属矿产分离技术进展. 化工矿物与加工. 2022(11): 19-31+37 .
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