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HUANG Lingyun. Crystal Structure Properties of Sphalerite and Copper Activation Effect[J]. Conservation and Utilization of Mineral Resources, 2018, (3): 26-30. DOI: 10.13779/j.cnki.issn1001-0076.2018.03.005
Citation: HUANG Lingyun. Crystal Structure Properties of Sphalerite and Copper Activation Effect[J]. Conservation and Utilization of Mineral Resources, 2018, (3): 26-30. DOI: 10.13779/j.cnki.issn1001-0076.2018.03.005

Crystal Structure Properties of Sphalerite and Copper Activation Effect

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  • Received Date: April 20, 2018
  • Publish Date: June 24, 2018
  • Issue Publish Date: June 24, 2018
  • The influence of crystal structure and copper activation on the flotation performance of sphalerite is introduced. The influence mechanism is further analyzed and concluded in terms of sphalerite surface properties, vacancy defects, impurity defects, and copper activation. Finally, these results could provide reference for basic research on flotation recovery and separation of sphalerite ore.

  • [1]
    戴自希.世界铅锌资源的分布、类型和勘查准则[J].世界有色金属, 2005(3):15-23. http://www.cnki.com.cn/Article/CJFDTOTAL-KCYD200201000.htm
    [2]
    刘红召, 杨卉芃, 冯安生.全球锌矿资源分布及开发利用[J].矿产保护与利用, 2017(1):113-118. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=8c635d74-95a7-4338-bd4b-7df9f58a90ec
    [3]
    袁莹, 祝新友, 王艳丽.我国铅锌矿床伴生稀散元素分布与赋存状态研究综述[J].矿物学报, 2011(S1):316-317. http://www.cnki.com.cn/Journal/A-A5-KWXB-2011-S1.htm
    [4]
    陈喜峰, 彭润民.中国铅锌矿资源形势及可持续发展对策[J].有色金属工程, 2008(3):129-132. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjs200803034
    [5]
    文金磊, 朱一民, 周菁, 等.铅锌矿产资源特征及浮选工艺研究现状[J].矿产综合利用, 2015(6):1-6. http://www.cnki.com.cn/Article/CJFDTotal-KCZL201604003.htm
    [6]
    叶志文, 文书明, 王伊杰, 等.都龙铁闪锌矿工艺矿物学研究[J].矿产保护与利用, 2018(1):107-111. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=d5fc1aff-5b9a-4d7e-b9be-f128408bd115
    [7]
    薛晨, 魏志聪.闪锌矿抑制剂的作用机理及研究进展[J].矿产综合利用, 2017(3):38-43. http://www.cnki.com.cn/Article/CJFDTOTAL-KCBH201506016.htm
    [8]
    童雄, 周庆华, 何剑, 等.铁闪锌矿的选矿研究概况[J].金属矿山, 2006(6):8-12. http://www.cqvip.com/QK/90084X/2006006/22086647.html
    [9]
    陈建华, 吴伯增, 陈波.脆硫铅锑矿与铁闪锌矿的浮选行为及其抑制[J].矿产保护与利用, 2005(4):27-30. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=13462afe-5dac-47e3-9db2-cd0c3c908e18
    [10]
    谢贤. 难选铁闪锌矿多金属矿石的浮选试验与机理探讨[D]. 昆明: 昆明理工大学, 2011. http://cdmd.cnki.com.cn/Article/CDMD-10674-1012262926.htm
    [11]
    Robertson, F. Sphalerite-dolomite orientation relations at the renfrew Zinc prospect, ontario[J]. American Mineralogist, 1951(1):116-122.
    [12]
    Harmer S L, Goncharova L V, Kolarova R, et al. Surface structure of sphalerite studied by medium energy ion scattering and XPS[J]. Surface Science, 2007(2):352-361. http://www.sciencedirect.com/science/article/pii/S0039602806010429
    [13]
    刘建. 闪锌矿表面原子构型及铜吸附活化浮选理论研究[D]. 昆明: 昆明理工大学, 2013.
    [14]
    Maksimov V I, Dubinin S F, Parkhomenko V D. Neutron diffraction study of the nano-inhomogeneities of the sphalerite crystal structure induced by magnetoactive 3 d, ions in Ⅱ-Ⅵ solid solutions[J]. Journal of Surface Investigation:X-ray, Synchrotron and Neutron Techniques, 2013(1):105-112. DOI: 10.1134/S1027451013010278
    [15]
    陈晔, 陈建华, 李玉琼, 等.空间结构对硫化矿物表面能带结构和电子性质的影响[J].中国有色金属学报, 2016(11):2403-2411. https://www.wenkuxiazai.com/doc/9dee7a75ba1aa8114431d9b0-3.html
    [16]
    胡为柏.浮选[M].北京:冶金工业出版社, 1983.
    [17]
    印万忠, 孙传尧.矿物晶体结构与表面特性和可浮性关系的研究[J].国外金属矿选矿, 1998(4):8-11. http://www.cqvip.com/qk/93727X/199804/3007499.html
    [18]
    Tong X, Song S, He J, et al. Activation of high-iron marmatite in froth flotation by ammoniacal copper(Ⅱ) solution[J]. Minerals Engineering, 2007(3):259-263.
    [19]
    Wright K, Watson G W, Parker S C, et al. Simulation of the structure and stability of sphalerite (ZnS) surfaces[J]. American Mineralogist, 2015(1):141-146. http://adsabs.harvard.edu/abs/1998AmMin..83..141W
    [20]
    CHEN Jianhua, CHEN Ye, LI Yuqiong, et al. Effect of vacancy defects on electronic properties and activation of sphalerite(110) surface by first-principles[J]. Journal of China nonferrous metals, 2010(3):502-506. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgysjsxb-e201003025
    [21]
    陈建华, 曾小钦, 陈晔, 等.含空位和杂质缺陷的闪锌矿电子结构的第一性原理计算[J].中国有色金属学报, 2010(4):765-771. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgysjsxb201004027
    [22]
    Solecki J, Komosa A, Szczypa J. Copper ion activation of synthetic sphalerites with various iron contents[J]. International Journal of Mineral Processing, 1979(3):221-228. http://www.sciencedirect.com/science/article/pii/0301751679900383
    [23]
    B. Gigowski, A. Vogg, K. Wierer, et al. Effect of Fe-lattice ions on adsorption, electrokinetic, calorimetric and flotation properties of sphalerite[J]. International Journal of Mineral Processing, 1991, 33:103-120. DOI: 10.1016/0301-7516(91)90046-L
    [24]
    Harmer S L, Mierczynska-Vasilev A, Beattie D A, et al. The effect of bulk iron concentration and heterogeneities on the copper activation of sphalerite[J]. Minerals Engineering, 2008(12-14):1005-1012. http://www.sciencedirect.com/science/article/pii/S0892687508000381
    [25]
    Boulton A, Fornasiero D, Ralston J. Effect of iron content in sphalerite on flotation[J]. Minerals Engineering, 2005(11):1120-1122.
    [26]
    张正阶, 胡天斗.闪锌矿中杂质Fe存在形式的重新认识[J].矿物学报, 1997(1):1-10. http://www.cqvip.com/qk/95783X/199701/2491302.html
    [27]
    Zhang Q, Rao S R, Finch J A. Flotation of sphalerite in the presence of iron ions[J]. Colloids & Surfaces, 1992(2):81-89. http://www.sciencedirect.com/science/article/pii/016666229280123J
    [28]
    Li J, Song K, Liu D, et al. Hydrolyzation and adsorption behaviors of SPH and SCT used as combined depressants in the selective flotation of galena from sphalerite[J]. Journal of Molecular Liquids, 2017, 231:485-490. DOI: 10.1016/j.molliq.2017.02.035
    [29]
    陈晔, 陈建华, 郭进.天然杂质对闪锌矿电子结构和半导体性质的影响[J].物理化学学报, 2010(10):2851-2856. DOI: 10.3866/PKU.WHXB20101001
    [30]
    Laskowski J S, Liu Q, Zhan Y. Sphalerite activation:flotation and electrokinetic studies[J]. Minerals Engineering, 1997(8):787-802. http://www.sciencedirect.com/science/article/pii/S0892687597000575
    [31]
    Andrea R Gerson, Angela G Lange, Kathryn E Prince, et al. The mechanism of copper activation of sphalerite[J]. Applied Surface Science, 1999(1-4):207-223. http://www.sciencedirect.com/science/article/pii/S0169433298004991
    [32]
    Siva Reddy G, Konda Reddy C. The chemistry of activation of sphalerite-a review[J]. Mineral Procesing and Extractive Metallurgy Review, 1988(1-2):1-38. DOI: 10.1080/08827508808952632
    [33]
    Ejtemaei M, Nguyen A V. A comparative study of the attachment of air bubbles onto sphalerite and pyrite surfaces activated by copper sulphate[J]. Minerals Engineering, 2017, 109:14-20. DOI: 10.1016/j.mineng.2017.02.008
    [34]
    Ralston J, Healy T W. Activation of zinc sulphide with Cu(Ⅱ), Cd(Ⅱ) and Pb(Ⅱ):Ⅰ. activation in weakly acidic media[J]. International Journal of Mineral Processing, 1980(3):175-201. http://www.sciencedirect.com/science/article/pii/0301751680900162
    [35]
    顾帼华, 王淀佐, 刘如意.硫酸铜活化闪锌矿的电化学机理[J].中南工业大学学报(自然科学版), 1999(4):374-377. https://www.wenkuxiazai.com/doc/b671bee3998fcc22bcd10d59.html
    [36]
    Harris P., K. Richter. The influence of surface defect properties on the activation and natural floatability of sphalerite[J]. Flotation of Sulphide Minerals, 1984(6):141-57.
    [37]
    Fornasiero D, Ralston J. Effect of surface oxide/hydroxide products on the collectorless flotation of copper-activated sphalerite[J]. International Journal of Mineral Processing, 2006(4):231-237. http://www.sciencedirect.com/science/article/pii/S0301751605001602
    [38]
    Wang J, Liu Q, Zeng H. Understanding copper activation and xanthate adsorption on sphalerite by time-of-flight secondary ion mass spectrometry, X-ray photoelectron spectroscopy, and in situ scanning electrochemical microscopy[J]. Journal of Physical Chemistry, 2013, 39:20089-20097. DOI: 10.1021/jp407795k
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