宏观大尺寸锂离子筛的制备与吸附应用研究进展

Research Progress on Preparation and Adsorption Application of Macroscopical Large Size Lithium−ion Sieves

  • 摘要: 锂是重要的战略资源,近年来随着新能源产业的快速发展,带动了金属锂及其化合物需求量的快速增长。我国已探明锂资源大多分布在盐湖卤水中,但其较高的镁锂比制约了大规模的开发利用。在众多的提锂方法中,锂离子筛吸附技术由于工艺简单、选择性高和可循环使用而被广泛研究,但人工制备的锂离子筛多为粉末状,难以回收和重复使用,不利于推广应用。通过造粒、铸膜等成型技术将锂离子筛构筑为宏观大尺寸吸附剂,能够有效弥补其在实际应用中的不足,对于加快推进盐湖卤水锂资源开发、实现我国锂资源自给自足具有重要意义。综述了锂离子筛的主要种类和发展现状、宏观大尺寸锂离子筛的常用制备方法以及宏观大尺寸锂离子筛在吸附提锂中的应用进展,最后对该技术进行了总结和展望。

     

    Abstract: Lithium is an important strategic resource. With the rapid development of new energy industry in recent years, the demand for lithium metal and its compounds has increased rapidly. Most of our proved lithium resources were distributed in salt lake brine, but the high magnesia lithium ratio restricted the large-scale development and utilization. Among the many methods of lithium extraction, lithium ion sieve adsorption technology has been widely studied because of its simple process, high selectivity and recyclability. However, the artificially prepared lithium ion sieve is mostly in powder form, difficult to recover and reuse, which is not conducive to popularization and application. By forming technologies such as granulation and casting film, lithium ion screen can be constructed as macro-size adsorbent, which can effectively make up for its deficiency in practical application, and has great significance for accelerating the development of salt lake brined lithium resources and realizing the self-sufficiency of Chinese lithium resources. In this paper, the main types and development status of lithium ion screen, the common preparation methods of macroscopic large size lithium ion screen, and the application progress of macroscopic large size lithium ion screen in adsorption and extraction of lithium are reviewed. Finally, the technology is summarized and prospected.

     

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