磷尾矿综合利用研究进展

Research Progress on Comprehensive Utilization of Phosphorus Tailings Resources

  • 摘要: 磷尾矿是磷矿选矿过程中产生的固体废弃物,伴随着中低品位磷矿的大规模开采和利用,其堆积量不断增加。中低品位磷矿的浮选尾矿主要由CaO、MgO、P2O5和SiO2组成,具有一定的开发利用价值。针对磷尾矿的化学性质、矿物成分及特点综述了磷尾矿的资源化利用现状与研究进展,阐述了从磷尾矿中再选回收P、Ca、Mg、Fe和K等有价元素,以及在制备建筑、农业、环保、充填和化工等领域资源化利用的研究,探讨了磷尾矿再选的关键问题,其核心在于浮选药剂的高效利用与联合工艺的协同优化;在建筑材料的应用方面,磷尾矿作为掺料、骨料及功能材料,兼具性能提升和环保效益;磷尾矿制备土壤调理剂和肥料潜力巨大,可作为重点方向研究;通过制备充填材料回填矿山,可实现尾矿减排、打造绿色矿山的目的;此外,将磷尾矿用于融雪剂等化工产品的制备,为磷化工产业的高值化转型和磷尾矿的消纳提供了新方向,同时进一步提升了磷尾矿的综合利用率。

     

    Abstract: Phosphorus tailings are a type of solid waste produced during the beneficiation process of phosphate ore. Due to the large−scale mining and utilization of medium−to−low−grade phosphate ore, the amount of tailings is continuously increasing. Flotation tailings from medium−to−low−grade phosphate ore are primarily composed of CaO, MgO, P2O5, and SiO2, and have potential value for development and utilization. This review focuses on the current status and research progress concerning the resource utilization of phosphorus tailings based on their chemical properties, mineral composition, and characteristics. It elaborates on research into the separation and recovery of valuable elements such as P, Ca, Mg, Fe, and K from phosphorus tailings, as well as their resource utilization in the preparation of materials for construction, agriculture, environmental protection, backfilling, and chemical industries. key issues in the re−separation of phosphorus tailings are discussed, with the focus being on the efficient utilization of flotation reagents and the synergistic optimization of combined processes. In the application of building materials, phosphorus tailings serve as admixtures, aggregates, and functional materials, offering both performance enhancement and environmental benefits. The preparation of soil conditioners and fertilizers from phosphorus tailings has significant potential and should be a key research direction. Preparing backfill materials for mine backfilling reduces tailings and enables the construction of green mines. Furthermore, utilizing phosphorus tailings for preparing chemical products such as deicing salts offers a new approach to the high−value transformation of the phosphorus chemical industry and the consumption of phosphorus tailings, simultaneously enhancing their overall utilization rate.

     

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