深海稀土选冶研究进展

Research Progress in Deep−Sea Rare Earth Mineral Processing and Extraction

  • 摘要: 稀土元素作为关键战略资源,在新能源材料、航空航天、军工制造等高技术产业中具有不可替代的作用。随着全球战略资源需求激增及深海矿产资源研究的突破,深海稀土矿的开采与利用逐渐成为国际矿产资源研究的热点领域。深海稀土元素主要赋存于黏土矿物含量高、矿物解离度低且粒度细微的深海沉积物中,深海沉积物作为一种新型的稀土资源,其储量远超陆地,尤其富含中重稀土元素,对保障未来高技术产业资源供给具有重大战略意义。稀土元素常以吸附态或类质同象形式存在于生物磷灰石等细微矿物颗粒内,导致其品位低、粒度细、解离困难,这对稀土元素的分离提取提出了更高要求。深海沉积物中稀土元素的分离和提取方法主要有湿法冶金技术、物理分选与选冶联合工艺、新兴的绿色低碳技术以及原位采集与初步富集工艺等。酸浸法虽流程简单,但存在酸耗高、回收率不理想及环境风险大等问题;相比之下,结合粒度分选与浮选的分级浮选—冶炼工艺,以及融合原位预富集、管道输送与模块化精炼的集成技术体系,在提高回收率、降低运输与环境成本方面展现出更大潜力。对此,针对海底采矿技术、选冶技术进行了大量的评估研究报道,结合经济效益、环境保护、资源潜力等因素对未来稀土元素分离提取技术进行预测。未来技术的发展需紧密结合稀土的具体赋存状态,优化选冶联合流程,并着力解决深海极端环境下的技术可行性与经济性问题。

     

    Abstract: Rare earth elements serve as critical strategic resources, playing an irreplaceable role in high−tech industries such as new energy materials, aerospace, and military manufacturing. As global demand for strategic resources continues to rise and research on deep−sea mineral resources advances, the extraction and utilization of deep−sea rare earth deposits have emerged as a key focus in international mineral resource studies. Deep−sea rare earth elements are predominantly hosted in sediments characterized by high clay mineral content, poor mineral liberation, and fine grain size. As a novel type of rare earth resource, deep−sea sediments hold reserves far exceeding those on land and are notably enriched in medium and heavy rare earth elements, offering significant strategic value for securing future supplies to high−tech industries. These elements often occur in adsorbed or isomorphous forms within fine mineral particles, such as biogenic apatite, resulting in low grades, fine particle sizes, and difficult liberation−posing considerable challenges for the development of efficient extraction technologies. Current methods for separating and extracting rare earth elements from deep−sea sediments include hydrometallurgical processes, combined physical separation and beneficiation techniques, emerging green and low−carbon technologies, and in−situ collection with preliminary enrichment systems. Although acid leaching features a relatively simple process, it is associated with high acid consumption, suboptimal recovery rates, and significant environmental risks. In contrast, integrated approaches−such as those combining particle size separation with flotation in a staged flotation−smelting process, or systems that incorporate in−situ pre−enrichment, pipeline transport, and modular refining−show greater promise for improving recovery efficiency while reducing transportation and environmental impacts. Numerous evaluation studies on seabed mining and beneficiation technologies have been reported, offering insights into future directions for rare earth separation and extraction methods by considering economic feasibility, environmental sustainability, and resource potential. Future technological development must be closely aligned with the specific occurrence states of rare earth elements, optimize integrated beneficiation−metallurgy flowsheets, and address the challenges of technical viability and economic feasibility under extreme deep−sea conditions.

     

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