高铁赤泥与高磷铁矿共还原焙烧—磁选制备铁

Iron Preparation through Co−reduction Roasting and Magnetic Separation of Iron−rich Red Mud and High Phosphorus Iron Ore

  • 摘要: 针对高磷铁矿脱磷困难及高铁赤泥堆存污染问题,提出利用工业固废高铁赤泥部分替代传统脱磷剂,通过共还原焙烧—磁选工艺同步回收高磷铁矿与高铁赤泥中的铁资源。系统考察了高铁赤泥占比、碳酸钙用量(协同脱磷)及二段磨矿对提铁降磷效果的影响,结合HSC热力学计算、XRD与SEM−EDS表征,揭示了共还原过程矿物转化机制。实验表明,在高铁赤泥占比25%、碳酸钙用量6%、温度1 200 ℃条件下进行还原焙烧60 min,焙烧后经两段磨矿—磁选获得了铁品位(Fe)达85.55%、磷(P)含量0.250%的还原铁产品,高磷铁矿与高铁赤泥的综合铁回收率达80.75%。还原温度为1 200 ℃时,氟磷灰石会发生分解并还原产生P2,而P2会与金属铁反应,进入金属铁相。当高铁赤泥与高磷铁矿共还原时,其碱性组分(CaO/Na2O)会优先结合焙烧体系中的SiO2和Al2O3,一定程度上可抑制氟磷灰石的分解和还原反应;为实现深度脱磷,添加碳酸钙协同高铁赤泥强化降磷,其分解产生的CaO能优先结合焙烧体系中的SiO2和Al2O3,进一步抑制氟磷灰石的分解和还原反应。该项基于固废的协同处理技术为难处理铁矿资源的清洁利用与赤泥的大宗消纳提供了可行路径。

     

    Abstract: In response to the difficulties in dephosphorization of high phosphorus iron ore and the pollution caused by the storage of iron−rich red mud, this study proposed their co−reduction roasting and magnetic separation. The aim was to replace traditional dephosphorization agents partly with iron−rich red mud and recover iron resources from high phosphorus iron ore and iron−rich red mud synchronously. The effects of red mud proportions, calcium carbonate dosages (collaborative dephosphorization) dosages, and secondary−grinding on iron extraction and dephosphorization were systematically investigated. Combined with HSC thermodynamic calculations, XRD, and SEM−EDS characterization, the mineral transformation mechanisms during co−reduction were revealed. Experiments have shown that when the proportion of iron−rich red mud is 25%, the dosage of calcium carbonate is 6%, the reduction temperature is 1 200 ℃ for 60min followed by two stages of grinding and magnetic separation, a direct reduced iron product obtained contains 85.55% iron (Fe) and 0.250% phosphorus (P). The corresponding comprehensive iron recovery rate is 80.75%. At the reduction temperature of 1 200 ℃, fluorapatite is decomposed and reduced to produce P2, which reacts with metallic iron and enters the metallic iron phase. When iron−rich red mud is co−reduced with high phosphorus iron ore, its alkaline components (CaO/Na2O) preferentially combine with SiO2 and Al2O3 in the roasting system, which inhibit the decomposition and reduction reactions of fluorapatite to some extent. In addition, it is necessary to use calcium carbonate in conjunction with iron−rich red mud to enhance dephosphorization. CaO produced by its decomposition can preferentially combine with SiO2 and Al2O3 in the calcination system, further inhibiting the decomposition and reduction reactions of fluorapatite. This study develops a collaborative processing technology based on solid waste, promoting clean utilization of refractory iron ore resources and the large consumption of red mud.

     

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