块状富油煤原位热解半焦组分演化和热解特征研究

Study on The Composition Evolution and Pyrolysis Characteristics of In Situ Pyrolysis Semi−coke of Massive Tar−rich Coal

  • 摘要: 以新疆三塘湖盆地白石湖矿区八道湾组富油煤为对象,采用加温加压的原位热解物理模拟实验模拟原位热解(轴压/围压15 MPa、升温速率10 ℃/min、温度区间为200~700 ℃)测定不同温度点产物含量、覆压孔渗实验测定煤样孔隙率演化规律(压力区间为4.14~15 MPa)、显微镜观察热解前后显微组分变化及COMSOL Multiphysics 6.2软件耦合多物理场模拟原位热解等方法,研究块状富油煤原位热解过程中半焦组分演化和热解特性。实验结果显示,半焦产量随温度升高持续下降,焦油产量呈“先升后降”抛物线型且在400 ℃时达到峰值,气体+损失随温度升高整体递增后急剧下降;压力条件下热解温度与孔隙度、渗透率呈非线性波动关系;显微组分方面,块状原煤与小颗粒粉煤热解后半焦显微组分含量呈现显著差异;数值模拟与物理模拟共同揭示压力场、孔隙度和渗透率随时间和温度的演化特征,400~600 ℃为热解最佳温度区间。研究结果可为该类型资源的地下原位开发提供理论支撑。

     

    Abstract: The tar−rich coal sample collected from the Badaowan Formation in the Baishihu Mining Area of the Santanghu Basin, Xinjiang was used in this study to investigate the component evolution and pyrolysis characteristics during the in situ pyrolysis. The methods employed included in situ pyrolysis physical simulation experiments, which were carried out under elevated temperature and pressure to measure the product contents at different temperature points. Overburden pressure pore permeability experiments were also performed to determine the evolution law of coal sample porosity. Furthermore, microscopic observations were made to examine the changes in maceral composition before and after pyrolysis, and COMSOL Multiphysics 6.2 software was utilized for multi−physics field−coupled simulation of in situ pyrolysis. Results show that semicoke yield continuously decreases as the temperature rises, while the tar yield exhibits a parabolic trend, initially increasing and then decreasing, reaching its peak at 400 ℃. The gas yield plus losses initially increase overall and then sharply decrease with the rising temperature. The overburden pressure pore permeability experiments indicate that a nonlinear fluctuating relationship exists between pyrolysis temperature, porosity, and permeability under pressure conditions. Significant differences are found in the semicoke maceral content after pyrolysis between bulk raw coal and small−particle pulverized coal. Both numerical and physical simulations jointly reveal that the evolutionary characteristics of the pressure field, porosity, and permeability over time and temperature are elucidated, with 400~600 ℃ being identified as the optimal temperature range for pyrolysis. This work can provide theoretical support for the underground in situ development of tar−rich coal resource.

     

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