稀土尾矿综合利用研究进展

Research Progress on Comprehensive Utilization of Rare Earth Tailings

  • 摘要: 随着科技和新兴产业的发展,稀土矿产资源的需求日益增加,但稀土尾矿大规模和高度集中的排放堆积,占用了大量的土地资源,且造成生态环境破坏和环境污染,稀土尾矿利用意义重大。稀土尾矿资源化利用的途径和方式较多:用于再选回收稀土、铁、铅和铌等有价金属以及萤石、重晶石和白云石等非金属矿物,但再选不能实现稀土尾矿的整体利用,再选后仍然会排放尾矿;用于制备脱硝催化剂、地质聚合物、分子筛、陶粒、陶瓷、微晶玻璃、水泥及砖等材料,可实现稀土尾矿的整体利用,且稀土尾矿中含有的稀土金属使其在制备脱硝催化剂、微晶玻璃、陶瓷及微波吸收材料方面具有独特的性能和用途,发挥出重要的作用,但可能受到有毒有害组分、工艺稳定性、低成本产业化应用、持续消纳等因素的制约。稀土尾矿资源化利用的途径和方式各有其优势和不足,针对稀土尾矿的化学成分、矿物组成、粒形及粒径等,宜因地制宜,对稀土尾矿进行分质分类针对性资源化利用,尤其是针对稀土尾矿中含有的稀土金属开发功能性材料进行高质、高值化利用,但在资源化利用中要避免重金属和放射性元素造成的二次污染。

     

    Abstract: With the development of technology and emerging industries, the requirement for rare earth mineral resources is increasing rapidly. However, the large−scale and highly concentrated discharge and accumulation of rare earth tailings occupy a large amount of land resources and cause ecological damage and environmental pollution, so it has a great significance of rare earth tailings utilization. There are many ways and methods for the resource utilization of rare earth tailings, which are used for reconcentration of valuable metals such as rare earths, iron, lead, niobium and non−metallic mineral minerals such as fluorite, barite and dolomite. However, reconcentration cannot achieve the overall utilization of rare earth tailings, and tailings will still be discharged after reprocessing. For the preparation of denitration catalysts, geopolymers, porous solid materials, ceramics, ceramic particles, microcrystalline glass, cement clinker, and bricks, it can achieve the overall utilization of rare earth tailings. The rare earth metals contained in rare earth tailings give them unique properties and uses in the preparation of denitration catalysts, microcrystalline glass, ceramics and microwave absorption materials. They play irreplaceable characteristics and roles, but may be constrained by toxic and harmful components, process stability, low−cost industrial applications and continuous consumption. The ways and methods for the resource utilization of rare earth tailings each have their own advantages and disadvantages. For the chemical composition, mineral composition, and particle size of rare earth tailings, it is appropriate to tailor them to local conditions, classify them according to their quality, and carry out targeted resource utilization. Especially for the high quality and high value utilization of functional materials containing rare earth metals in rare earth tailings, it is necessary to avoid secondary pollution caused by heavy metal ions and radioactive elements in resource utilization.

     

/

返回文章
返回